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Yes, definitely.
Election systems on most countries nowadays still rely on centralized servers to store election data which are vulnerable to third-party hacking or even worse being hacked by the current government. Blockchain technology can provide a tamper-proof election database so one individual can't vote more than once (or other security measures on other voting systems).
There are problems that can come by implementation of blockchain technology though. Below are the ones that comes on top of my head:
Blockchain technology is still extremely new. I believe it will be able to solve fraud problems on election systems but I think we still need to think of more perfect designs before we implement it on real-world election because it is something vital.