Angular Momentum in Quantum Mechanics

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angular momentum in quantum mechanics

Good day, Steemit community.

Today, I am going to discuss the angular momentum in quantum mechanics. Classically, angular momentum is the vector cross product between the position vector with the linear momentum vector. It is typically associated with the circular motion of the body. In quantum mechanics, angular momentum's is not a vector anymore but an operator. And it was found to possess some important implication in the property of a quantum system.

Angular Momentum


The vector-angular momentum alt has the following Cartesian components:

alt

and, therefore,

alt

The eigenvalue spectrum for this operator is given by

alt

On the other hand, the eigenvalue of one of its component alt is

alt

We can also show that,

alt

And this implies that the operator alt and alt have a set of common eigenfunctions labelled by the quantum numbers l and m. This shared eigenfunction is called the spherical harmonics alt:

alt

Since

alt

only, one of the components of alt can be well defined.

Spherical Harmonics

The spherical harmonics are given by the expression

alt

where the alt are the associated Legendre functions, defined by

alt

The normalization constants alt are given by

alt

The alt are polynomials of order l (power series in w containing a finite number of powers of w, the highest being $w^l$), called Legendre polynomials, and are polynomial solutions of Legendre's equation
alt

The Legendre polynomial are defined on the interval alt and normalized by the requirement that

alt

Legendre polynomials have the parity of l, that is, they are even functions of w if the integer l is even and odd function of w if l is odd.

Angular Momentum in Quantum Mechanics | Ecency