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Santiago Canizares was the unluckiest Spanish goal keeper
After Andoni Zubizarreta took his spot in the 90s, Canizares won the right to be Spain's first-choice at the 2002 World Cup but dropped an aftershave bottle in the build up, severed the tendon in his toe and was forced to miss out.
Then a certain Iker Casilas came along and Canizares was forgetten forever.
https://www.mirror.co.uk/sport/row-zed/weird-injuries-asensio-real-madrid-5266185.amp