Bicarbonate
Acetic=Carboxylic
Metalloenzyme
the idea Niacin & Sulfur is creating a Deprotonation effect by Chelation of Iron, Potassium & Magnesium.
the original idea was to chelate the mycoplasma lipid structure, the conclusion is the essential minerals were stripped instead.
the oppsite ideas is Bicarbonate Carboxylic Acetic will cause Protonation of essential minerals to remineralize what toxic acids of mycoplasma.
this is the oppsite of my original conclusion.
mixing living vinegar with full spectrum minerals breaks down into monoatomic ions, that replicates bone broth.
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New mechanistic studies on the proline-catalyzed aldol reaction
https://www.pnas.org/doi/10.1073/pnas.0307979101
Enamine/Transition Metal Combined Catalysis: Catalytic Transformations Involving Organometallic Electrophilic Intermediates
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6858407/
An Aldol Switch Discovered in Stilbene Synthases Mediates Cyclization Specificity of Type III Polyketide Synthases
https://www.cell.com/cell-chemical-biology/fulltext/S1074-5521(04)00224-8
Carbanion
https://www.sciencedirect.com/topics/chemistry/carbanion
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Polyketide
Aldol Reaction
Carbonyl Reduction
https://en.m.wikipedia.org/wiki/Magnesium_chloride
https://en.m.wikipedia.org/wiki/Aldol_reaction
https://en.m.wikipedia.org/wiki/Polyketide
https://en.m.wikipedia.org/wiki/Carbonyl_reduction
https://en.m.wikipedia.org/wiki/Methylene_group
https://en.m.wikipedia.org/wiki/Hydride
https://en.m.wikipedia.org/wiki/Hydrogen_anion
https://en.m.wikipedia.org/wiki/Cannizzaro_reaction
https://en.m.wikipedia.org/wiki/Nucleophilic_acyl_substitution
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Magnesium chloride is a Lewis acid catalyst in aldol reactions.
Stereogenic aldol units are especially common in polyketides, a class of molecules found in biological organisms. In nature, polyketides are synthesized by enzymes that effect iterative Claisen condensations.
Polyketides are a class of natural products derived from a precursor molecule consisting of a chain of alternating ketone (or reduced forms of a ketone) and methylene groups.
A methylene group is any part of a molecule that consists of two hydrogen atoms bound to a carbon atom.
The evolutionary history of fatty acid synthases are very much intertwined with that of polyketide synthases (PKS).
Polyketide synthases use a similar mechanism and homologous domains to produce secondary metabolite lipids.
Polyketide antibiotics, antifungals, cytostatics, anticholesteremic, antiparasitics, coccidiostats, animal growth promoters and natural insecticides.
Polyketide Examples:
Antihelminthics:
Ivermectin
Pesticides (Insecticide):
Spinosad or Spinosyn
Tetracyclines:
Antibiotic Agent
Doxycycline
Ansamycins:
Antitumor Agents
Macbecin
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Hydrogen anion electrons in negative ions come from the ionization of metals with low first ionization potentials, including the alkali metals and alkali earths.
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Hydrogen Anion
Hydride
Cannizzaro Reaction
Nucleophilic Acyl substitution
Aldol Condensation
Self-Condensation
RE: Protonation Cation/Anion