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In 1666, Sir Isaac Newton first recorded the fact that, when visible light was passed through a prism, it was split to produce a continuous spectrum of rainbow colours that contained all the wavelengths of light.
You are not going to get all wavelengths of light. A prism refracts light. Microwaves are not going to appear when you refract light from the sun using a prism :P
RE: Molecules in Interstellar Space and a Close Look at Electrons