I was going to say that caterpie isn't a word... then i read the post and googled it and saw that yes caterpie is a word in the pokemon universe...
I am not much familiar with pokemons...
You can use a very light dark tone on top of the color to make them darker. the going twice or thrice doesn't really work, though the dark might make it look a bit muddy
RE: Pokemon Drawing#10 Caterpie